9478 / 2027
Nuclear Physics overview

Full chapter

Nuclear Physics

All 10 topics and the revision summary on one page.

01

Evidence for the nucleus

Make a guess. You are not marked.

In the alpha-scattering experiment, a very few alpha particles bounced almost straight back from thin gold foil. What did this show?

  1. The gold atoms are packed so tightly that alpha particles cannot pass.
  2. The positive charge and most of the mass are in a tiny central nucleus.
  3. Electrons in the gold atoms are heavy enough to reflect alpha particles.
Show the answer

The positive charge and most of the mass are in a tiny central nucleus.

Only a very dense, positively charged centre could turn a fast alpha particle right round. That so few did shows the nucleus is tiny compared with the atom.

Rutherford scattering connects a pattern of observations to an atomic model. Most alpha particles pass almost straight through a thin foil; rare large deflections reveal a small concentration of positive charge and mass.

A narrow beam of positively charged alpha particles encounters a thin metal foil, and a detecting screen records their outgoing directions. Distinguish the observed deflection pattern from the explanation inferred from it.

A narrow beam, a thin foil and a detecting screen

A narrow beam, a thin foil and a detecting screenA shielded alpha source at the left sends a narrow beam through a collimating slit towards a thin foil. A curved detecting screen surrounds much of the foil, with an opening for the incident beam. Dashed radial guides identify forward, sideways and backward detector positions; they indicate observation directions, not a claim that alpha trajectories kink at the foil. Most detected alpha particles have small deflection; a small fraction have large deflection and very few return towards the source. Source, foil and screen are schematic apparatus sizes. The following enlarged nucleus view has a separate scale.αSourceSlitThin foilDetecting screenGuides mark observation directions.Apparatus is schematic.

The screen records where particles arrive. Most have little deflection; a small fraction turn through large angles. The selected direction guides do not represent the relative number of events or the detailed path near a nucleus.

Enlarged view: repulsion bends the paths continuously

Enlarged view: repulsion bends the paths continuouslyFour selected model alpha trajectories enter from the left with rightward initial motion and pass a positive nucleus at the centre. Their acceleration is everywhere radially outward. None touches the symbolic nuclear surface. The near-central path turns continuously and emerges towards the left; more distant paths turn less. The horizontal and vertical distances share one scale. This enlarged comparison does not represent atom-to-nucleus sizes or measured scattering frequencies, and adds no required scattering formula.Selected enlarged pathsIncident motion is initially rightward.+Positive nucleusNo hard-ball impact is drawn.Paths are not a frequency sample.

A positive alpha particle is repelled by concentrated positive charge. These smooth paths show the mechanism of deflection. The symbolic nucleus and the surrounding atom are not drawn on one size scale, and four selected paths cannot indicate how often each deflection occurs.

The first view identifies the source, narrow beam, foil and detecting screen. The second is an enlarged view of continuous repulsive paths near a positive nucleus. The selected paths illustrate directions, not the relative numbers of events; the nucleus and whole atom are not shown on one size scale.
Scattering observations and the nuclear model they support
ObservationInference
Most alpha particles have little deflection.Most of the atom's volume does not contain the concentrated positive charge and mass.
A small fraction have large deflections; very few scatter backwards.A close approach to a small, massive, positive nucleus can strongly repel an alpha particle.

Large deflections are not explained by alpha particles striking individual light electrons. Nor does this experiment by itself identify the neutron or establish all electronic energy levels. Its central result is the existence of a nucleus much smaller than the whole atom.

Read nuclide notation

A nucleus is represented by . The nucleon number A, also called mass number, counts protons plus neutrons. The proton number Z, also called atomic number, counts protons and identifies the element.

Protons = Z
Neutron number N = A - Z
Electrons in a neutral atom = Z

Here N denotes the neutron number of one nucleus. When N later denotes a sample population, the stated context changes its meaning.

Isotopes have the same Z but different neutron numbers. For example, chlorine-35 and chlorine-37 both have 17 protons, but contain 18 and 20 neutrons respectively.

Worked isotope and ion count

Changing electrons does not change the isotope

A neutral atom has 17 protons, 20 neutrons and 17 electrons. Losing one electron produces a singly positive ion with 16 electrons. Its nucleus still has A = 37 and Z = 17.

Do not subtract an electron from the nuclear proton number. A is a particle count, not an exact measured mass of A atomic mass units.

For a sample population, N = (m/M)NA, with sample mass m and supplied molar mass M in matching units. NA = 6.02 × 1023 mol-1; a few times 10-4 mol therefore contain order 1020 entities. Name those entities: one atom has one nucleus, but usually many nucleons. The particle-counting explanation gives the mole and relative-mass foundations.

Check your understanding

Most alpha particles pass through a thin foil with little deflection, while very few are scattered through large angles or backwards. Which inference is supported?

  1. Large deflections are caused by collisions with individual electrons carrying most of the atomic mass.
  2. The positive nucleus fills most of the atom, and the experiment directly identifies its neutrons.
  3. Positive charge and most atomic mass are concentrated in a small nucleus.
Show the answer

Positive charge and most atomic mass are concentrated in a small nucleus.

Most paths avoid a close approach to the small concentration, while a rare close approach to its positive charge can strongly repel an alpha particle. The observations support a nucleus much smaller than the whole atom.

02

Alpha, beta and gamma

Make a guess. You are not marked.

Alpha, beta and gamma radiation pass through the same magnetic field. Which is deflected most, and in which sense?

  1. Alpha, because it carries the larger charge of the two.
  2. Beta, much more than alpha, and in the opposite direction.
  3. Gamma, because it has the most energy.
Show the answer

Beta, much more than alpha, and in the opposite direction.

Beta particles have a tiny mass, so they curve far more tightly than alpha particles. Their charge is negative, so they curve the opposite way.

Radiation type determines what is emitted and how it interacts. Penetration and ionisation comparisons also depend on its energy and the material through which it travels.

The nature and characteristic interactions of three nuclear emissions
EmissionNature and chargeTypical comparison in a stated absorber
Alpha, αA helium-4 nucleus: two protons and two neutrons, charge +2e, mass approximately 4 u.Dense ionisation over a short range; ordinary alpha radiation can be absorbed by paper or a thin barrier.
Beta-minus, β-An electron produced in a nuclear process, charge -e, electron rest mass.Intermediate penetration and ionisation in the comparison; a suitable thin metal or plastic absorber can greatly reduce transmission.
Gamma, γAn electromagnetic photon with no charge or rest mass.Generally much more penetrating, with less direct ionisation along the path. Thick dense shielding attenuates it.

A beta electron is not a pre-existing orbital electron simply leaving the atom. Gamma emission reduces nuclear energy without changing its nucleon or proton count. Zero photon rest mass does not mean zero photon energy or momentum.

Compare transmission with a stated absorber

Compare transmission with a stated absorberThree separate schematic rows share the same source and detector positions. The alpha row places a thin paper barrier between them and has no transmitted alpha arrow. The beta-minus row uses a suitable plastic or metal absorber and retains a transmitted arrow labelled reduced count. The gamma row uses thick dense shielding and retains a transmitted arrow labelled reduced count: shielding attenuates gamma rather than making transmission identically zero. Barrier width and radiation arrow width are qualitative, with no supplied material thickness, energy, count efficiency or universal stopping range.α: alphaThin paperNo alpha throughβ-: beta-minusSuitable plastic / metalReduced countγ: gammaThick dense shieldingReduced countSourceDetector

Absorption and attenuation depend on the emitted energy and the material. These ordinary school-source comparisons do not assign a universal range. A reduced transmitted count is not a statement that every surviving photon has lost the same fraction of its energy.

The sign of charge determines the initial bending direction

The sign of charge determines the initial bending directionRadiations initially travel right into a magnetic field directed into the page, shown by crosses. A positive alpha trajectory curves upwards; a beta-minus electron trajectory curves downwards; the gamma ray remains straight. The two charged curves use equal illustrative radii only to show opposite signs, not to compare real radii. The field does not exert an electric-charge magnetic force on gamma photons. Momentum, charge and field strength, not charge alone, set a charged particle path radius.B into the pageEntryα (+)β- (-)γNo radius comparison is implied.

For the same rightward entry and field into the page, positive charge is forced up and negative charge down. The curves are schematic: their radii do not compare the particles' momenta. A cross here denotes magnetic field into the page, not current.

The absorber comparison keeps the geometry fixed and shows attenuation, not an absolute universal stopping thickness. The separate field view has entry to the right and B into the page: alpha bends up, beta-minus down, and gamma is not magnetically deflected. Curvatures are qualitative; charge alone does not determine their relative radii.

Charged alpha and beta particles also experience electric forces in opposite directions in a given electric field. Gamma has no electric charge force. Charged-particle speeds depend on their kinetic energies and are below c; gamma travels at c in vacuum.

A penetration statement must name the radiation energy and absorber context. Gamma is not completely stopped by one universal thickness, and short alpha range does not imply weak ionisation. For living tissue, an internal alpha-emitting material can deposit energy densely close to its location.

Check your understanding

Why does the short range of ordinary alpha radiation not make an alpha-emitting substance inside the body harmless?

  1. Short range means that no energy is transferred to matter.
  2. Alpha radiation becomes gamma radiation after entering tissue.
  3. It can produce dense ionisation close to the material inside tissue.
Show the answer

It can produce dense ionisation close to the material inside tissue.

Range, ionisation and source location all matter. A thin external barrier can absorb ordinary alpha radiation, but an internal emitter can deposit energy in nearby living tissue.

03

Random decay and measured counts

Make a guess. You are not marked.

A detector records 100 counts in one minute from a long-lived source, then 89 counts in the next minute. Has the source changed?

  1. Yes, the detector must have moved further from the source.
  2. Yes, it has lost 11% of its nuclei in one minute.
  3. Not necessarily, because random decay makes equal-time counts vary.
Show the answer

Not necessarily, because random decay makes equal-time counts vary.

Each decay is random, so counts in equal intervals scatter around a mean even when the source is steady. A change of 11 in 100 is within that scatter.

An individual decay is unpredictable, while a large collection has a statistical trend. A detector records counts, which must be interpreted using the observation time, its response and the background.

Spontaneous means nuclear decay does not need an external triggering event. Random means we cannot predict the exact time at which a particular unstable nucleus will decay. Ordinary changes of temperature, pressure or chemical state do not provide a way to set that time in this model.

Activity is not automatically count rate

Activity is the rate of nuclear decays. Its unit is the becquerel:

1 Bq = 1 decay/s
Detector count rate = recorded counts / counting time

Some emissions miss the detector or are not registered, while background adds other counts. An activity and a count rate therefore need not be numerically equal. Bq is a decay-rate unit, not a radiation-dose unit. Here activity A is distinct from a nuclide's nucleon number A.

Identify the background contribution

Background includes cosmic radiation and natural radionuclides in the environment, materials and bodies. Artificial sources can also contribute. A comparable background measurement excludes the investigated source while retaining the relevant detector and surroundings.

Keep the detector conditions fixed for the background comparison

Keep the detector conditions fixed for the background comparisonTwo schematic arrangements use the same detector, counter connection and source position. In the upper view the source is present and points towards the detector window; the fixed spacing is marked d. In the lower view the investigated source is absent, shown by an empty dashed position, while the detector and counter remain in the same places. Background still contributes counts. The cable connects each detector to its corresponding counter; these are two conditions of the same arrangement, not two independent efficiencies or simultaneous sources.Source presentDetectord unchangedCounterSourceInvestigated source absentDetectorBackgroundd unchangedCounterRemoved

Measure source-plus-background and background as separate conditions with otherwise comparable settings. Use each actual interval to calculate a rate. The source is absent for background; subtracting an unmatched raw count would not make the rates comparable.

Equal intervals fluctuate around a statistical mean

Equal intervals fluctuate around a statistical meanFive separate supplied source-plus-background counts for successive equal ten-second intervals are 412, 389, 405, 394 and 400. Points are not joined by a smooth decay curve. The horizontal axis is interval number one to five. The count axis deliberately starts at 380, not zero, and ends at 420. A horizontal dashed line at 400 identifies the mean count, not a measured constant at every instant. These constructed records are separate from the varying-duration workbook series.Count in 10.0 s380390400410420Mean 40012345Interval numberVertical axis starts at 380 counts.

Each point is a count in 10.0 s. Their mean is 400 counts per interval, giving a total rate of 40.0 counts/s. Scatter about this mean does not by itself imply detector failure or a smoothly falling source activity.

The source-detector arrangement identifies the quantities to hold fixed; the background condition excludes the investigated source. The separate points are the supplied equal-10 s counts, not a smooth decay curve. Their count-axis lower limit is shown explicitly.

Worked background correction

Convert counts to rates before subtracting

A rate of order 40 counts/s over 10 s gives hundreds of counts; background of order 4 counts/s gives tens. These constructed teaching records describe a source whose expected rate changes negligibly during the short observations. Each interval lasts 10.0 s.

Separate source-plus-background and background records, each counted for 10.0 s
IntervalSource + backgroundBackground
141238
238942
340536
439444
540040
Total rate = 2000 counts / 50.0 s = 40.0 counts/s
Background rate = 200 counts / 50.0 s = 4.0 counts/s
Net source rate = 40.0 - 4.0 = 36.0 counts/s

The corresponding means are 400 and 40 counts per 10.0 s. If durations differ, subtract their rates, not the unmatched raw counts. Pool a stable-rate series using total counts divided by total duration rather than an unweighted mean of unequal-duration rates.

Fluctuations between equal intervals are evidence of the random nature of decay, not proof that the detector is broken. A smooth expected decay curve does not mean each nucleus decays on schedule.

Evaluate the counting method

Compare rates with source-detector positions, absorber, detector window and timing method fixed. A longer observation can reduce fractional random scatter when the expected rate is sufficiently stable, but it can blur a rapid decay change. Repetition does not correct an omitted background, incorrect time interval or changed geometry.

Changing detector efficiency and dead time at high rates can limit the result. Background can fluctuate or drift too. Retain the supplied records and explain a specific limitation rather than deleting points simply to obtain a smoother pattern.

Check your understanding

Constructed source-plus-background records total 2000 counts in 50.0 s. Comparable background records total 200 counts in 50.0 s. What is the net source count rate?

  1. 1800 counts/s.
  2. 40.0 counts/s.
  3. 36.0 counts/s.
Show the answer

36.0 counts/s.

The total rate is 2000/50.0 = 40.0 counts/s and background rate is 200/50.0 = 4.0 counts/s. Their difference is 36.0 counts/s.

04

Half-life and corrected curves

Make a guess. You are not marked.

Two samples contain the same radioactive nuclide. Sample B has twice as many undecayed nuclei as sample A. How do their half-lives and activities compare?

  1. Same half-life. B has twice the activity.
  2. B has twice the half-life and twice the activity.
  3. Same half-life and the same activity.
Show the answer

Same half-life. B has twice the activity.

Half-life is a property of the nuclide, not of the amount. Activity is lambda times the number of nuclei, so twice the nuclei means twice the decays per second.

Half-life is the time for the expected number of undecayed parent nuclei, or the activity, to fall to half its initial value. For a detector reading, use the source contribution and check that the conditions make it proportional to the decaying population.

For a single unchanged radionuclide, the expected number of undecayed parent nuclei and the activity halve over the same interval. A proportional net source count rate does too when detection conditions remain fixed. Half-life is not the lifetime of every individual nucleus.

After one, two and three half-lives, the remaining fractions are 1/2, 1/4 and 1/8. A few half-lives leave a fraction, not zero. Match time units before comparing: 0.2 min is 12 s, while 2 min is 120 s.

Separate total rate from the source trend

In this supplied model, net source rate starts at 80.0 counts/s and halves every 120 s. Background remains 4.0 counts/s. These are instantaneous expected rates at the named times, not long-window measured averages.

Expected net and total count rates in the 120 s half-life model
t / sNet / counts s-1Total / counts s-1
08084
1204044
2402024
3601014
48059

Total expected rate approaches the background

Total expected rate approaches the backgroundBoth decay panels use identical time and rate scales, over zero to 480 seconds. The expected source rate begins at 80 counts per second and halves every 120 seconds. Adding a constant background of four counts per second gives total values 84, 44, 24, 14 and 9 at successive 120-second times. The curve tends towards the dashed background line; it never becomes that value at a finite time. The marked values are ideal instantaneous model rates, not raw counts or long-window averages.Total rate / counts s-10204060800120240360480t / sBackground: 4

The same fixed background is added at every time. Half of the initial raw total is 42 counts/s; that is not the correct halving target for the source. At 120 s the total is 44 counts/s.

Corrected expected rate halves in equal times

Corrected expected rate halves in equal timesBoth decay panels use identical time and rate scales, over zero to 480 seconds. The expected source rate begins at 80 counts per second and halves every 120 seconds. Subtracting the background gives 80, 40, 20, 10 and 5 counts per second at successive 120-second times. Guides identify 80 to 40 and 40 to 20 with two adjacent 120-second brackets. The smooth expected net rate tends towards zero, not to a negative activity and not to zero at a finite plotted time. The marked values are ideal instantaneous model rates, not raw counts or long-window averages.Net rate / counts s-10204060800120240360480t / s120 s120 s

The two marked intervals each last 120 s even though the absolute decrease is smaller in the second interval. A proportional corrected rate shares the half-life only while source and detection conditions remain fixed.

Both expected-rate plots use the same time and rate scales. Total approaches the 4 counts/s background; net approaches zero. Equal 120 s spans halve the corrected rate from different starting points.

Half of the initial raw total is 42 counts/s, but the total at one half-life is 44 counts/s: 40 from the source plus 4 background. Read half-life from the corrected quantity. The falling trend becomes less steep as fewer parents remain; it is not a constant rate of loss.

Worked transfer problem

Count the halvings

A corrected rate decreases from 72 to 9 counts/s in 15 min under fixed detection conditions:

72 → 36 → 18 → 9
Three half-lives = 15 min
Half-life = 5.0 min

One eighth of the initial rate represents three halvings, not eight. A small negative background-subtracted estimate near zero can arise from fluctuations; it is not negative physical activity.

Try it step by step

Work it out in steps: Number of half-lives, then Fraction of nuclei remaining, then Activity remaining in Bq.

  1. Problem 1. A source has an activity of 1200 Bq and a half-life of 8.0 hours. Find its activity after 24 hours.
  2. Problem 2. A source has an activity of 5000 Bq and a half-life of 15 minutes. Find its activity after 60 minutes.
  3. Problem 3. A source has an activity of 8000 Bq and a half-life of 2.0 days. Find its activity after 10 days.
Show the answer

Problem 1.

Number of half-lives: 24 / 8.0 = 3 half-lives

Fraction of nuclei remaining: Fraction = (1/2)3 = 0.125

Activity remaining in Bq: A = 1200 x 0.125 = 150 Bq

Problem 2.

Number of half-lives: 60 / 15 = 4 half-lives

Fraction of nuclei remaining: Fraction = (1/2)4 = 0.0625

Activity remaining in Bq: A = 5000 x 0.0625 = 313 Bq (3 sf)

Problem 3.

Number of half-lives: 10 / 2.0 = 5 half-lives

Fraction of nuclei remaining: Fraction = (1/2)5 = 0.03125

Activity remaining in Bq: A = 8000 x 0.03125 = 250 Bq

The exponential model relates this shape to decay constant, activity and a logarithmic data fit.

Try it step by step

Work it out in steps: Decay constant lambda = ln 2 / half-life in per hour, then Activity A = A0 e^(-lambda t) in Bq.

  1. Problem 1. A source has a half-life of 10 hours and an initial activity of 2000 Bq. Find its activity after 5.0 hours.
  2. Problem 2. A source has a half-life of 6.0 hours and an initial activity of 900 Bq. Find its activity after 4.0 hours.
  3. Problem 3. A source has a half-life of 20 hours and an initial activity of 1500 Bq. Find its activity after 30 hours.
Show the answer

Problem 1.

Decay constant lambda = ln 2 / half-life in per hour: lambda = 0.693 / 10 = 0.0693 per hour

Activity A = A0 e^(-lambda t) in Bq: A = 2000 x e^(-0.0693 x 5.0) = 2000 x 0.707 = 1410 Bq (3 sf)

Problem 2.

Decay constant lambda = ln 2 / half-life in per hour: lambda = 0.693 / 6.0 = 0.116 per hour

Activity A = A0 e^(-lambda t) in Bq: A = 900 x e^(-0.116 x 4.0) = 900 x 0.630 = 567 Bq (3 sf)

Problem 3.

Decay constant lambda = ln 2 / half-life in per hour: lambda = 0.693 / 20 = 0.0347 per hour

Activity A = A0 e^(-lambda t) in Bq: A = 1500 x e^(-0.0347 x 30) = 1500 x 0.354 = 530 Bq (3 sf)

Check your understanding

With fixed detection conditions, a background-corrected rate falls from 72 to 9 counts/s in 15 min. What is the half-life?

  1. 7.5 min.
  2. 1.875 min.
  3. 5.0 min.
Show the answer

5.0 min.

72 to 36 to 18 to 9 is three half-lives. Therefore each half-life is 15/3 = 5.0 min.

05

Activity and exponential decay

The decay constant describes the chance of decay per nucleus per unit time. A large population follows a predictable expected trend even though each individual decay remains random.

Let N be the number of undecayed parent nuclei and λ the decay constant. For a sufficiently short interval Δt, the probability that one parent nucleus decays is approximately λΔt. The unit of λ is s-1 when time is in seconds.

Activity A = λN
N = N0e-λt
A = A0e-λt

Activity is the expected decay rate, in Bq: one decay per second. A constant λ means a constant fractional decay rate, not a constant number of decays per second. As N decreases, A decreases. The cumulative number that have decayed is N0 - N, which increases.

These equations describe one parent radionuclide with constant decay constant. They do not make its individual nuclei decay at predetermined times, and a mixture need not have one exponential total activity.

Connect decay constant and half-life

At t = t1/2, half the original parent population remains:

1/2 = e-λt1/2
ln(1/2) = -λt1/2
λ = ln(2)/t1/2

A half-life of order 100 s suggests λ of order 10-2 s-1. For the supplied 120 s half-life, λ = 0.00577623 s-1. Convert minutes to seconds before using that value with a time.

Worked activity and detector rate

Decay rate is a property of the source

A separate sample initially contains N0 = 6.00 × 105 parent nuclei and has half-life 120 s:

A0 = λN0
= 3465.74 Bq ≈ 3.47 × 103 Bq

After 240 s, two half-lives have elapsed. N = 1.50 × 105 and A = 866.434 Bq, approximately 866 Bq.

Suppose a supplied calibration for this unchanged setup counts 5.00% of decays, with one relevant emission per decay. Its initial net detector rate is then:

r0 = 0.0500A0
= 173.287 counts/s

This is a different source from the 80 counts/s model below. The fraction detected is supplied calibration information, not a universal conversion between counts/s and Bq. Detector geometry, response and attenuation matter.

Use ratios and logarithms

With constant detection conditions and correctly subtracted background, the source count rate is proportional to activity:

r/r0 = e-λt
ln(r/r0) = -λt

The logarithm's argument is a dimensionless ratio. A plot of ln(r/r0) against t has gradient -λ. For the 120 s model, the time to reach 10.0% is:

t = -ln(0.10)/λ
= 398.631 s ≈ 399 s

A logarithm turns the supplied fractional model into a straight line

A logarithm turns the supplied fractional model into a straight lineThe corrected rate ratio is r divided by r-zero, with r-zero eighty counts per second. The vertical quantity is its natural logarithm and is dimensionless. At times 0, 120, 240, 360 and 480 seconds its values are 0, minus ln 2, minus 2 ln 2, minus 3 ln 2 and minus 4 ln 2. The time scale matches the preceding curves. The straight line has decreasing numerical value as time increases; the arrowed time axis is at logarithm zero. No zero or negative rate is logged.ln(r/r0) (dimensionless)00-0.693120-1.386240-2.079360-2.773480t / sPositive ratios only.

This graph is the supplied model ln(r/r0) = -ln(2)t/120, with time in seconds. Its gradient is about -0.00578 per second. The logarithm acts on a dimensionless positive ratio; the zero ordinate means r = r0, not r = 0.

The expected net rate follows the supplied 120 s model. Its dimensionless logarithmic ratio gives a straight line with gradient -λ. A raw source-plus-background rate does not obey this same straight-line relation.

Zero and negative corrected rates have no real logarithm. A positive value very close to background can also have large relative uncertainty; being mathematically loggable does not make it a reliable fitting point.

Try it step by step

Work it out in steps: Decay constant lambda = ln 2 / t1/2 in s-1, then Activity A = lambda N in Bq.

  1. Problem 1. A sample contains 2.0 x 1015 nuclei of a nuclide with half-life 8.0 days. Find its activity. (1 day = 86400 s.)
  2. Problem 2. A sample contains 1.0 x 1020 nuclei of a nuclide with half-life 5.3 years. Find its activity. (1 year = 3.16 x 107 s.)
  3. Problem 3. A sample contains 5.0 x 1012 nuclei of a nuclide with half-life 6.0 hours. Find the decay constant and the activity.
Show the answer

Problem 1.

Decay constant lambda = ln 2 / t1/2 in s-1: t1/2 = 8.0 x 86400 = 6.91 x 105 s, so lambda = 0.693 / 6.91 x 105 = 1.00 x 10-6 s-1

Activity A = lambda N in Bq: A = 1.00 x 10-6 x 2.0 x 1015 = 2.0 x 109 Bq

Problem 2.

Decay constant lambda = ln 2 / t1/2 in s-1: t1/2 = 5.3 x 3.16 x 107 = 1.67 x 108 s, so lambda = 0.693 / 1.67 x 108 = 4.14 x 10-9 s-1

Activity A = lambda N in Bq: A = 4.14 x 10-9 x 1.0 x 1020 = 4.14 x 1011 Bq

Problem 3.

Decay constant lambda = ln 2 / t1/2 in s-1: t1/2 = 6.0 x 3600 = 21600 s, so lambda = 0.693 / 21600 = 3.21 x 10-5 s-1

Activity A = lambda N in Bq: A = 3.21 x 10-5 x 5.0 x 1012 = 1.60 x 108 Bq

Graph reader

Find a half-life from measured counts

A detector records the total count rate from a source plus background. Move the time cursor to read the graph.

050100150200250300051015202530time / mincount rate / (counts/min)

Check your understanding

A sample initially contains 6.00 x 105 parent nuclei and has half-life 120 s. With lambda = ln(2)/120 s-1, what is its activity at 240 s?

  1. About 3466 Bq, because the decay constant is unchanged.
  2. 1.50 x 105 Bq.
  3. About 866 Bq.
Show the answer

About 866 Bq.

Two half-lives leave N = 1.50 x 105. A = lambda N = (ln2/120)(1.50 x 105) = 866 Bq. A count rate need not equal the activity because geometry and registration matter.

Paper 4 practice: spreadsheet

Preserve the counts, then calculate rates

Open the counts and decay workbook, or import the raw count CSV. These are constructed teaching records. The working workbook contains formulas and charts; inspect and reproduce the calculations rather than treating the file as an experiment you performed.

For CSV import, choose comma separation and keep the start, duration and count columns numeric. Create sheets named Rates and Decay. Import the complete CSV into Rates starting at A10. If it opens in A1:F16 on a separate raw-import sheet, preserve that sheet and copy the entire block to Rates A10:F25. This places the headers and records at the cells used below.

You can also type the supplied records into those same cells manually. Retain the record IDs, series and data-status labels alongside the numbers. The Motion data method explains numeric import, formula copying and XY plots.

On Rates, headers are in A10:F10: record ID, series, start time in s, duration in s, total count and data status. Source-plus-background records S01-S05 occupy rows 11-15; background records B01-B03 occupy 16-18; decay records D01-D07 occupy 19-25. Each series uses its own time origin.

Keep these raw columns intact. A blank is not a measured zero. Resolve missing readings or non-positive durations before calculating or fitting; the stated ranges do not automatically expand when records are added.

Pool counts using the actual duration

The S records contain 4000 counts in 100 s; the B records contain 720 counts in 180 s. These separate stable-rate series give 40.0 total, 4.0 background and 36.0 net counts/s. The unweighted mean of the five S rates is 40.1533 counts/s, which gives equal weight to unequal counting durations.

Rates B4: pooled background rate
=SUM(E16:E18)/SUM(D16:D18)
Rates B5: pooled total rate
=SUM(E11:E15)/SUM(D11:D15)
Rates B6: net stable-source rate
=B5-B4
G11: interval midpoint, in s
=C11+D11/2
H11: total rate, in counts/s
=E11/D11
I11: background-subtracted rate
=IF(B11="background","",H11-$B$4)

Copy G11:I11 down through row 25. The fixed reference $B$4 keeps the same background rate. Do not average the entire decaying series into one rate to estimate its time dependence.

Make the logarithmic selection explicit

On Decay, B4 contains reference rate 80 counts/s, B5 contains expected half-life 120 s, and B6 contains =LN(2)/B5. Label A10:F10 as record ID, midpoint, net rate, ratio, logarithm and status. Rows 11-17 link to the seven D records:

A11: record ID; B11: midpoint
=Rates!A19=Rates!G19
C11: corrected rate; D11: dimensionless ratio
=Rates!I19=C11/$B$4
E11: logarithm only for positive rate
=IF(C11>0,LN(D11),"")
F11: retain the reason for an absent logarithm
=IF(C11>0,"positive","not logged")

Copy A11:F11 through row 17. The first five D records are rounded expected counts over finite windows; the final two deliberately illustrate fluctuations near background.

Constructed decay records after background subtraction
RecordMidpoint / sNet / counts s-1
D01279
D0212040
D0324020
D0436010
D054805
D06960-0.1
D0712000

Keep all seven records. The last two are background-subtracted estimates, not negative or zero claims about the source's expected activity. Their logarithm cells remain blank, rather than being replaced with numerical zero.

Decay E4: fitted decay constant, in s-1
=-SLOPE(E11:E15,B11:B15)
E5: free intercept of the log fit
=INTERCEPT(E11:E15,B11:B15)
E6: fitted half-life, in s
=LN(2)/E4

This specified fit uses D01-D05 only. It does not force the intercept to zero. For genuine records, preserve all readings and justify the range using the method and uncertainty; do not remove points merely to make a line straighter.

Compare the expected and fitted trends

A22:A82 contains model times 0 to 1200 s in 20 s steps. Use these formulas and copy B22:D22 through row 82:

B22: expected net rate
=$B$4*EXP(-$B$6*A22)
C22: expected total including background
=B22+Rates!$B$4
D22: net rate from the free-intercept fit
=$B$4*EXP($E$5-$E$4*A22)

Use an XY chart with numeric midpoint time in s horizontally and corrected count rate in counts/s vertically. Show all seven records as individual markers, with the expected and fitted trends separately labelled. A second XY chart plots only E11:E15 against B11:B15, with dimensionless ln(r/r0) vertically and the fitted straight line. Do not join the record markers into an apparently observed continuous path.

Display the fitted numeric equation beside the log graph, using the intercept in E5 and negative gradient -E4. The working workbook does this in H43. For the supplied records it is approximately ln(r/r0) = -0.00061647 - 0.005774516t, with t in seconds and gradient unit s-1. Keep the underlying coefficient cells at full precision.

Compare the calculated results

The fitted λ is 0.005774516 s-1, the log intercept is -0.00061647, and the fitted half-life is 120.0355 s. These are close to the supplied generating values, but not identical.

A finite-window rate approximates the instantaneous midpoint rate. In this model, the 20 s early counting window changes that relation by about 0.05562%. Together with rounding to integer counts, this explains the small fitted difference; it is not evidence of a faulty real detector.

Keep full stored precision and format only the displayed values. Changing a supplied input should update its derived midpoint, rate and fit; preserve an original copy before exploring such changes. Long windows collect more counts but blur a rapidly changing rate.

With actual records, also consider random counting scatter, uncertainty or drift in background, timing, detector dead time, geometry and efficiency changes, and more than one radionuclide. Agreement with a constructed model is a calculation check. The measurement-record method explains how to preserve actual readings, instrument information and justified exclusions when analysing an investigation.

06

Choose radiation for a task

Make a guess. You are not marked.

Why is gamma radiation, not alpha, used to sterilise syringes in sealed packs?

  1. Gamma is more strongly ionising than alpha, so it kills more bacteria.
  2. Gamma passes through the packaging to reach the syringes inside.
  3. Alpha would make the syringes radioactive, but gamma does not.
Show the answer

Gamma passes through the packaging to reach the syringes inside.

Gamma is very penetrating, so it reaches every part of the sealed pack and kills bacteria there. Alpha would be stopped by the packaging.

A useful source must interact in the required way and remain suitable for the time involved. Explain both its penetration or ionisation and its half-life, using the stated task.

Measure sheet thickness

Place a radiation source and detector on opposite sides of a sheet. For a suitable beta source and sheet material, some particles are absorbed and some are transmitted. Greater thickness then produces a lower corrected detector rate when the geometry and other conditions stay fixed.

A source absorbed almost completely by even the thinnest sheet gives little useful contrast. A source that passes through all the relevant thicknesses almost unchanged also gives poor sensitivity. Choose radiation that is partially transmitted over the required thickness range.

The source half-life should be long enough for useful output over the operating and calibration period, or the expected decay must be allowed for. A falling rate caused by source decay must not be interpreted automatically as a thicker sheet.

A partially transmitting sheet allows a thickness comparison

A partially transmitting sheet allows a thickness comparisonTwo schematic comparison rows use the same source and detector positions, identical incident direction and the same sheet centre. The upper sheet has drawing width eight and the lower has width twenty-six; these are qualitative thicknesses, not material data. A beta source sends radiation through the sheet towards a detector. Under otherwise fixed conditions the thicker sheet gives a lower transmitted count rate. Both rows show some transmission; neither complete absorption nor almost unchanged transmission is the intended sensitive regime. This is a conceptual industrial gauge, not a handling procedure.Same source and detector geometryβThinner sheetHigher rateSourceβThicker sheetLower rateSourceBoth cases allow partial transmission.

Compare thickness only while the source output, detector geometry, sheet material and other relevant conditions are controlled. A falling source activity could also reduce the count, so it must not be mistaken for a thicker sheet.

The source is inside; the detector receives photons outside

The source is inside; the detector receives photons outsideA schematic body outline contains a small internal tracer marker. Four gamma-photon direction arrows begin at that marker and leave in different directions; one reaches the external detector on the right. The detector is physically outside the body, separated from its outer edge. The figure does not place the source in the detector, make all emissions travel towards it, or specify a clinical dose or organ-specific uptake. Body proportions, source size and arrow counts are schematic.DetectorTracerOnly some emitted photonsreach the detector.

The emitted photons must escape the tissue to be detected externally. Only part of the emission reaches and is registered by the detector. A suitable half-life must also fit preparation and measurement, alongside the stated chemical and biological requirements.

The thickness gauge compares partial transmission with fixed source and detector positions. The tracer view places the emitting material inside the body and the detector outside: photons must escape the tissue to be detected. Arrows identify radiation paths, not movement of the radioactive material.

Detect an internal tracer

For external detection of a tracer within the body, suitable emitted photons must penetrate tissue and reach the detector. The distribution of the tracer provides information about the stated organ or process; its chemical suitability also matters.

The half-life must allow preparation and measurement while avoiding unnecessarily prolonged radioactive activity. Physical half-life describes nuclear decay; it does not by itself give the time for biological clearance from the body.

Compare supplied candidate properties

Meet both detection and timing conditions

In a simplified selection, all other suitability conditions are supplied as equal. A detector outside the body must receive photons, and at least half the initial activity must remain after 60 min. Consider fictional candidates emitting alpha with a 2 h half-life, gamma with a 1 min half-life, or gamma with a 2 h half-life.

The gamma emitter with a 2 h half-life meets both conditions. After 60 min it retains 2-1/2, approximately 0.707, of its initial activity. The alpha choice fails the specified external photon-detection requirement; the 1 min gamma choice decays far too quickly for the stated time.

This comparison uses the supplied conditions. The longest half-life is not automatically best for every application.

Deliver radiation to a treatment target

In external treatment, sufficiently penetrating radiation can reach a target within tissue. Ionisation deposits energy and can damage cells, which is the intended effect in the target but also a concern for surrounding tissue. Direction and exposure distribution matter alongside radiation type.

The source must maintain suitable output over its operating period, with decay allowed for. A long half-life reduces the rate of output change but also means the source remains radioactive for longer. Half-life alone does not determine a treatment's suitability.

Sterilise items through packaging

Penetrating gamma radiation can reach microorganisms inside suitable final packaging. Ionisation damages them without requiring the package to be opened. The source must provide useful output over the processing interval, and its changing activity must be allowed for as it ages.

Explain the hazard in context

Ionisation can damage living cells and genetic material. Relevant factors include activity, emitted energy and radiation type, exposure time, distance, shielding, and whether radioactive material enters the body. Short alpha range can limit an external exposure while an internal alpha emitter deposits energy densely near its location.

Irradiation means exposure to radiation. Contamination means radioactive material is present on or inside an object. Ordinary irradiation does not necessarily make the object radioactive; do not confuse the radiation reaching an object with the source material moving onto it.

Check your understanding

A tracer inside a pipe must be detected from outside it, and at least half its initial activity must remain after 60 min. Which radiation and half-life meet both conditions?

  1. An alpha emitter with a 2 h half-life.
  2. A gamma emitter with a 1 min half-life.
  3. A gamma emitter with a 2 h half-life.
Show the answer

A gamma emitter with a 2 h half-life.

It supplies photons and retains 2^(-60/120), about 0.707, of its activity after 60 min. Gamma photons pass through the pipe wall to the detector, so both conditions are met.

07

Balance nuclear equations

Make a guess. You are not marked.

Uranium-238, proton number 92, emits an alpha particle. What are the nucleon and proton numbers of the daughter nucleus?

  1. Nucleon number 238 and proton number 90.
  2. Nucleon number 234 and proton number 90.
  3. Nucleon number 234 and proton number 92.
Show the answer

Nucleon number 234 and proton number 90.

An alpha particle is 4 nucleons and 2 protons. 238 - 4 = 234 and 92 - 2 = 90, which is thorium.

A nuclear equation accounts for nucleon number and electric charge. Balance both before identifying an unknown product; energy and momentum must also be conserved in the complete process.

In , A counts nucleons and Z counts protons. For an emitted particle, the lower number records its charge in units of +e. An electron therefore has lower number -1 even though it contains no negative proton.

Alpha emission

→+

An alpha particle carries four nucleons and charge +2e. The daughter therefore has A reduced by 4 and Z reduced by 2. Here 238 = 234 + 4 and 92 = 90 + 2.

Beta-minus emission

→+

This displays the nucleon and charge account: 14 = 14 + 0 and 6 = 7 - 1. Within the nucleus, a neutron changes into a proton. The total nucleon number stays the same, while the daughter's proton number rises by one.

The emitted electron is produced by the nuclear process, rather than removed from an atomic shell. The displayed A/Z account is not a claim that only two products carry energy and momentum: an additional uncharged particle also participates.

The beta-decay evidence explains why the electron and daughter alone cannot account for the observations.

Gamma emission

→+ γ

The star indicates a higher-energy nuclear state. A gamma photon carries away energy and momentum; the nucleus has the same A and Z afterwards. The energy change does not require a change of element or isotope.

A reaction can have an incoming particle

+→+

Both sides contain 18 nucleons and charge +9e. A and Z balance across all incoming and outgoing particles, not just the two nuclei that look most prominent.

Conserved nucleon number does not mean conserved rest mass. A change of total rest mass can accompany a change in kinetic or radiation energy while total mass-energy remains conserved.

Check your understanding

In beta-minus decay, a parent nucleus has nucleon number A and proton number Z. What are the daughter values in the nucleon/charge account?

  1. A - 4 and Z - 2.
  2. A and Z - 1.
  3. A and Z + 1.
Show the answer

A and Z + 1.

A neutron-to-proton change leaves the total nucleon count unchanged. The new proton raises nuclear Z by one, while the emitted electron carries charge number -1.

08

What beta decay reveals

Make a guess. You are not marked.

Beta-minus particles from one nuclide come out with a range of kinetic energies, not one fixed energy. What did this suggest?

  1. The nucleus emits electrons from different shells of the atom.
  2. Energy is not conserved in nuclear decay, so the amounts vary.
  3. A second particle, the antineutrino, carries away the rest of the energy.
Show the answer

A second particle, the antineutrino, carries away the rest of the energy.

Each decay releases the same total energy. The varied electron energies showed that another, hard-to-detect particle shares it: the antineutrino.

Beta decay gives evidence for an additional particle through both the spread of electron energies and the momentum that is missing from an electron-and-daughter account.

Test the two-product prediction

Consider a parent nucleus initially at rest and a fixed decay branch to a specified daughter state. If only an electron and that daughter were produced, momentum conservation would require equal and opposite momenta. Together with the fixed energy available, this would fix the electron's energy.

Instead, beta electrons from that branch have a continuous range of energies up to an endpoint. The energy varies because it is shared with another emitted particle as well as the recoiling daughter. The extra particle is uncharged and difficult to detect; in beta-minus decay it is an antineutrino.

Electron energies form a continuous spread

Electron energies form a continuous spreadA schematic electron kinetic-energy spectrum occupies a continuous range from zero to an endpoint E-max. The horizontal coordinate is kinetic energy divided by E-max. The vertical quantity is a qualitative count density with no numerical normalisation. A separate dashed vertical guide at the endpoint identifies the one fixed electron energy predicted by an ideal two-body decay from a parent at rest on a fixed branch. It is not a second measured finite-width distribution and its guide height is not a count. The continuous spectrum is evidence that another participant shares the available energy and momentum.Electron count density(schematic vertical scale)Two-body prediction00.51Electron kinetic energy / EmaxThe endpoint guide is not a count.

A fixed two-body decay of a parent initially at rest would give a fixed electron energy for that branch. The observed spread motivates an additional energy carrier while preserving conservation. This schematic adds no independent event energy or isotope-specific endpoint.

Translate momenta head to tail to test the complete account

Translate momenta head to tail to test the complete accountThe parent is initially at rest, so total momentum is zero. Three translated vectors use an equal horizontal and vertical scale in one common momentum unit, p-zero. From the starting point O, the electron vector goes three units right. From its tip, the daughter vector goes three units left and four units down. The missing vector then goes four units up, returning to O and closing the triangle. Thus the vector sum is zero. These momentum vectors are translated without rotation; they are not spatial particle trajectories. No separate kinetic-energy values, masses or real isotope are attached to this illustrative event.Parent initially at restTranslated momentum vectorspe = (3, 0)p0pd(-3, -4)p0pmissing(0, 4)p0OThe final tip returns to O.+x+ype+pd+pmissing= 0p0 is one common momentum unit.These arrows are not trajectories.

The electron and daughter momenta alone leave a downward resultant. An additional upward momentum closes the account. An unobserved neutral carrier can conserve energy and momentum; the diagram does not justify abandoning either conservation law.

The spectrum illustrates a continuous electron-energy distribution for a fixed branch; the endpoint guide marks the two-product prediction, not a measured narrow peak. The separate vector example closes the momentum account with an additional particle. Its arbitrary momentum scale is not a calibrated event from the spectrum, and the translated vectors are not trajectories.

Supplied momentum account

Find the missing vector

The parent is at rest. The supplied electron and daughter momenta in a planar example, in units of a common momentum p0, are:

pelectron = (3, 0)p0
pdaughter = (-3, -4)p0
Sum = (0, -4)p0

The total initial momentum is zero, so the missing particle must carry (0, +4)p0. Adding this vector closes the account. Adding only the two momentum magnitudes would discard their directions and give the wrong result.

The energy distribution and momentum imbalance support an additional carrier. They are not a reason to abandon energy or momentum conservation. Balancing nucleon number and charge alone would not have revealed the missing energy and momentum.

Check your understanding

For one beta-decay branch of a parent initially at rest, electrons have a continuous energy spread and the measured electron-plus-daughter momentum does not close the account. What inference retains conservation?

  1. An additional neutral particle carries energy and momentum.
  2. The electron is an orbital electron, so its energy need not enter the nuclear account.
  3. Energy and momentum cease to be conserved in nuclear processes.
Show the answer

An additional neutral particle carries energy and momentum.

A third participant permits variable sharing of the available energy and completes the vector momentum account. In beta-minus decay this carrier is an antineutrino.

09

Mass defect and binding energy

A bound nucleus has less rest mass than its separated nucleons. The corresponding energy difference is the energy required to separate the nucleus completely.

Use mass units consistently

The unified atomic mass unit u is defined as one twelfth of the mass of a neutral carbon-12 atom. For these supplied calculations use 1 u = 1.66 × 10-27 kg. Nucleon number A is dimensionless; it is not an exact mass in u.

Worked conversions

Keep the type of particle in the mass label

A neutral chlorine-37 atom has supplied mass 36.966 u:

ma = 36.966(1.66 × 10-27)
= 6.136356 × 10-26 kg
≈ 6.14 × 10-26 kg

This is an atomic mass, including electrons, not a bare nuclear mass. Conversely, a supplied electron mass 9.11 × 10-31 kg is:

me/u = (9.11 × 10-31)/(1.66 × 10-27)
me ≈ 5.49 × 10-4 u

The rounded nuclear masses used below contain no orbital electrons. Proton and neutron masses are close to, but not exactly, 1 u.

Supplied nuclear masses for the binding and fusion calculations
Particle or nucleusMass / u
Proton, mp1.00727647
Neutron, mn1.00866492
Deuteron, hydrogen-2 nucleus2.01355321
Triton, hydrogen-3 nucleus3.01550072
Alpha particle, helium-4 nucleus4.00150618

Convert an energy difference from mass

Mass and energy are equivalent through E = mc2, where c is the speed of electromagnetic waves in vacuum; use the supplied value 3.00 × 108 m/s. A change of rest mass Δm corresponds to an energy change ΔE = Δmc2. For a complete nuclear process, a decrease in total rest mass can supply kinetic energy and radiation while total mass-energy is conserved.

One electronvolt is the energy transferred to a charge of magnitude e through a potential difference of 1 V. With supplied e = 1.60 × 10-19 C:

1 eV = 1.60 × 10-19 J
1 MeV = 1.60 × 10-13 J
Supplied conversion: 1 u c2 = 931.5 MeV

A mass difference of order 10-3 u gives an energy of order 1 MeV, about 10-13 J per nucleus. This is a useful scale check before a precise subtraction. An eV is a unit of energy, not electric potential.

Binding energy is a positive separation energy

For a nucleus with Z protons and A - Z neutrons, the positive mass defect is:

Δm = Zmp + (A - Z)mn - mnucleus
Binding energy = Δmc2

The separated nucleons have greater rest energy. Forming the bound nucleus releases this energy difference; separating it completely requires the same amount to be supplied. A nucleus does not keep radiating its binding energy merely because it remains bound.

The same nucleons have different total rest energies

The same nucleons have different total rest energiesA convenient energy reference puts a separated free proton and neutron at zero. The bound deuteron is lower by 2.22459 megaelectronvolts. A downward brown arrow represents energy released when those free nucleons bind; an equal-length upward blue arrow represents the energy input required to separate the deuteron completely into the same proton and neutron. Both arrows span the same levels. The diagram deletes no nucleon and draws no ongoing emission from a nucleus that simply remains bound. The numerical zero is a relative energy reference, not zero rest mass.Relative energy / MeV0-2.22459Free proton + neutronBound deuteron (p + n)ReleaseInputEqual energy difference:2.22459 MeVNo nucleon disappears.

Binding releases the positive energy difference; complete separation requires that same energy input. The deuteron still contains one proton and one neutron. Its total binding energy is about 2.22 MeV, whereas its binding energy per nucleon is about 1.11 MeV.

The separated proton and neutron define relative energy zero. The bound deuteron is lower by 2.22459 MeV. Equal-sized arrows show energy released on formation and energy required for separation; vertical position represents energy, not physical height.

Worked deuteron

Total and per-nucleon binding energy

A deuteron contains one proton and one neutron. Using the supplied nuclear masses:

Δm = 1.00727647 + 1.00866492 - 2.01355321
= 0.00238818 u
Binding energy = 0.00238818(931.5)
= 2.22458967 MeV ≈ 2.22 MeV

In joules this is approximately 3.56 × 10-13 J. There are two nucleons, so the binding energy per nucleon is 2.22458967/2 = 1.11229 MeV per nucleon, approximately 1.11 MeV per nucleon.

Keep the mass digits until after subtraction: the defect is much smaller than either original mass. Use one consistent conversion route rather than mixing differently rounded constants. If a problem supplies atomic masses instead, account for electron masses consistently; do not silently mix atomic and nuclear masses.

Try it step by step

Work it out in steps: Mass defect in u, then Binding energy in MeV (1 u = 931.5 MeV), then Binding energy per nucleon in MeV.

  1. Problem 1. A helium-4 nucleus has mass 4.001506 u. Proton mass = 1.007276 u, neutron mass = 1.008665 u. Find its binding energy per nucleon.
  2. Problem 2. A carbon-12 nucleus has mass 11.996709 u. Proton mass = 1.007276 u, neutron mass = 1.008665 u. Find its binding energy per nucleon.
  3. Problem 3. An oxygen-16 nucleus has mass 15.990525 u. Proton mass = 1.007276 u, neutron mass = 1.008665 u. Find its binding energy per nucleon.
Show the answer

Problem 1.

Mass defect in u: Mass defect = 2 x 1.007276 + 2 x 1.008665 - 4.001506 = 0.030376 u

Binding energy in MeV (1 u = 931.5 MeV): BE = 0.030376 x 931.5 = 28.3 MeV

Binding energy per nucleon in MeV: BE per nucleon = 28.3 / 4 = 7.07 MeV (3 sf)

Problem 2.

Mass defect in u: Mass defect = 6 x 1.007276 + 6 x 1.008665 - 11.996709 = 0.098937 u

Binding energy in MeV (1 u = 931.5 MeV): BE = 0.098937 x 931.5 = 92.2 MeV

Binding energy per nucleon in MeV: BE per nucleon = 92.2 / 12 = 7.68 MeV (3 sf)

Problem 3.

Mass defect in u: Mass defect = 8 x 1.007276 + 8 x 1.008665 - 15.990525 = 0.137003 u

Binding energy in MeV (1 u = 931.5 MeV): BE = 0.137003 x 931.5 = 127.6 MeV

Binding energy per nucleon in MeV: BE per nucleon = 127.6 / 16 = 7.98 MeV (3 sf)

Check your understanding

A deuteron contains two nucleons and has binding mass defect 0.00238818 u. Use 1 u c2 = 931.5 MeV. Which statement distinguishes total from per-nucleon binding energy?

  1. About 1.11 MeV total and 2.22 MeV per nucleon.
  2. About 2.22 MeV for both quantities.
  3. About 2.22 MeV total and 1.11 MeV per nucleon.
Show the answer

About 2.22 MeV total and 1.11 MeV per nucleon.

Delta m c2 = 2.22459 MeV binds the whole deuteron. Dividing by its two nucleons gives 1.11229 MeV per nucleon.

10

Energy from fission and fusion

A reaction releases energy when its products have less total rest mass than its reactants. The binding-energy-per-nucleon curve helps explain why both the fusion of light nuclei and the fission of heavy nuclei can do this.

Read the binding-energy curve

Binding energy per nucleon rises rapidly across the light nuclei, reaches a broad maximum near nucleon numbers 50-60 in the iron/nickel region, then decreases gradually for heavier nuclei. It measures an average binding energy, not the total binding energy of a nucleus.

Binding energy per nucleon on the actual nucleon-number scale

Binding energy per nucleon on the actual nucleon-number scaleThe vertical axis is binding energy per nucleon from zero to nine megaelectronvolts per nucleon. The horizontal axis is nucleon number 1 to 240 on a uniform numerical scale. The values at nucleon numbers 2 and 4 correctly remain close to the left boundary rather than being artificially spread across the graph. The approximate anchors pair nucleon numbers 1, 2, 4, 16, 56, 92, 141 and 235 with binding energies per nucleon 0, 1.11, 7.07, 8.0, 8.8, 8.6, 8.3 and 7.6 MeV respectively. The trend rises sharply for light nuclei, has a broad maximum near nucleon number 56 and then falls gradually for heavy nuclei. The smooth connecting curve is an approximate trend through supplied anchors, not a precision measured isotope dataset. Individual isotopes can have additional local structure.Binding energy per nucleon/ MeV per nucleon0369160120180240Peak regionNucleon number AApproximate trend; equal A spacing.

The steep light-nucleus rise is compressed by the true horizontal scale. Read the separate enlarged panel below for A = 2 and A = 4. Energy release for a reaction still requires the complete, balanced initial and final account.

Light nuclei: a separately enlarged nucleon-number range

Light nuclei: a separately enlarged nucleon-number rangeThe vertical axis is binding energy per nucleon from zero to nine megaelectronvolts per nucleon. This separately labelled horizontal enlargement covers nucleon number zero to twenty. The trend begins with a single nucleon; no nucleus with zero nucleons is plotted. The same vertical scale as the main plot is retained. Approximate anchors are 1.11 MeV per nucleon at nucleon number 2, 7.07 at nucleon number 4, and 8.0 at nucleon number 16. The smooth connecting curve is an approximate trend through supplied anchors, not a precision measured isotope dataset. Individual isotopes can have additional local structure.Binding energy per nucleon/ MeV per nucleon03690248121620Nucleon number AHorizontal enlargement: A = 0 to 20

Only the horizontal range is enlarged here; the vertical quantity and scale are unchanged. A larger total binding energy is not automatically a larger binding energy per nucleon. The curve is an approximate trend, not an exact isotope mass table.

The main plot preserves the actual spacing of nucleon number A. The separate A = 0 to 20 view enlarges the light-nucleus region horizontally. These are approximate trend illustrations; the ordinate is binding energy per nucleon, not total binding energy.

Products with greater total binding energy have lower total rest energy for the same complete nucleon account. Multiply each nucleus's binding energy per nucleon by its own A before comparing totals. Local isotope differences exist, and this curve alone does not determine a reaction rate or every kind of nuclear stability.

For a sketch question

Label these features when you sketch the curve

Put nucleon number A on the x-axis and binding energy per nucleon (in MeV) on the y-axis. Then show these features:

  1. A steep rise for light nuclei. Hydrogen-2 is only about 1.1 MeV per nucleon.
  2. Helium-4 sits above its neighbours. At about 7.1 MeV per nucleon it is a spike above hydrogen-3, helium-3 and lithium-6. Helium-4 is unusually tightly bound.
  3. A broad peak of about 8.8 MeV per nucleon near A = 56. Label it iron or nickel. These are the most tightly bound nuclei.
  4. A slow fall for heavy nuclei. Uranium is down to about 7.6 MeV per nucleon at A = 235 to 238.
  5. Mark the two directions. Draw an arrow up the left side labelled "fusion" and an arrow up the right side, towards the peak, labelled "fission".

Explain fission and fusion in mark-scheme order

A common 3-mark question asks why both fission and fusion release energy. Write the links in this order:

  1. Fusion: light nuclei are on the rising part of the curve. When they join, the product has a higher binding energy per nucleon.
  2. Fission: a heavy nucleus is past the peak. When it splits into two medium nuclei, the products are nearer the peak and have a higher binding energy per nucleon.
  3. In both cases the total binding energy of the products is greater than that of the reactants. So the products have less total rest mass. This mass difference Δm is released as energy, E = Δmc2, mostly as kinetic energy of the products.

Iron and nickel sit at the peak. Neither fusing nor splitting them raises the binding energy per nucleon, so neither process releases energy from them.

Fusion combines light nuclei

In the supplied deuterium-tritium reaction, a hydrogen-2 nucleus and a hydrogen-3 nucleus form an alpha particle and a neutron:

+→+

Both sides have five nucleons and charge +2e. Use all products when comparing rest masses. The supplied nuclear masses, in u, are 2.01355321, 3.01550072, 4.00150618 and 1.00866492 in the displayed order.

Worked fusion energy

Include the outgoing neutron

Δm = (2.01355321 + 3.01550072)
- (4.00150618 + 1.00866492)
= 0.01888283 u
Q = 0.01888283(931.5)
= 17.5894 MeV ≈ 17.6 MeV

Here Q is the total energy released per complete reaction, using supplied 1 u c2 = 931.5 MeV. Leaving out the neutron would give a huge false mass deficit. Positive released energy does not remove the initial electric repulsion between the positively charged reactants.

Put these in order

Explain why energy is released when a uranium-235 nucleus undergoes fission. Put the links in order.

Show the answer

1. A slow neutron is absorbed by a uranium-235 nucleus, making it unstable. The unstable nucleus cannot hold together and splits.

2. The nucleus splits into two smaller nuclei and two or three neutrons. The fragments sit nearer the peak of the binding energy per nucleon curve than uranium does.

3. The fragments have a higher binding energy per nucleon than uranium-235, so the total binding energy increases. A larger total binding energy means the products are lighter than the reactants.

4. The total mass of the products is less than the total mass of the reactants. The missing mass is released as energy according to E = (change in m) c2.

5. The mass difference appears as kinetic energy of the fragments and neutrons, E = (change in m) c2.

Fission splits a heavy nucleus

One possible neutron-induced fission channel is:

+→++ 3

The totals are A = 236 and charge +92e on both sides. Other fragment combinations are possible; this is one supplied channel, not a unique outcome of every fission event.

Approximate supplied binding energies for a fission estimate
NucleusABinding energy / MeV per nucleon
Uranium-2352357.60
Barium-1411418.30
Krypton-92928.60
Initial total binding = 235(7.60) = 1786.0 MeV
Final total binding = 141(8.30) + 92(8.60)
= 1170.3 + 791.2 = 1961.5 MeV
Energy released ≈ 1961.5 - 1786.0
= 175.5 MeV

Free neutrons contribute no nuclear binding energy. This is an estimate from the supplied rounded averages, not a precision energy value for the channel. The products are more tightly bound overall, so the decrease in total rest energy is available as kinetic energy and radiation.

For both fusion and fission, compare the complete initial and final accounts. Subtracting two per-nucleon values without weighting by nucleon number does not give the reaction energy.

Check your understanding

For deuteron + triton -> alpha particle + neutron, supplied nuclear masses are 2.01355321, 3.01550072, 4.00150618 and 1.00866492 u respectively. With 1 u c2 = 931.5 MeV, what is the total released energy?

  1. About 3.52 MeV.
  2. About 17.6 MeV.
  3. About 957 MeV, using the alpha particle alone as the final mass.
Show the answer

About 17.6 MeV.

Initial minus final rest mass is 2.01355321 + 3.01550072 - 4.00150618 - 1.00866492 = 0.01888283 u. Multiplying by 931.5 gives 17.5894 MeV.

Revision

Nuclear Physics at a glance

Identify what is being counted, what is actually detected and which energy account is complete. Those decisions come before substituting numbers.

Structure and evidence

Most alpha particles passing a thin foil are little deflected; rare large deflections support a small concentration of positive charge and mass. A nucleus has Z protons and A - Z neutrons. A neutral atom has Z electrons. Isotopes have the same Z and different neutron counts; ionisation changes electrons without changing the nucleus.

Radiation and detection

Alpha is a helium-4 nucleus, beta-minus an electron from a nuclear process, and gamma an electromagnetic photon. Alpha and beta have opposite electric-force directions; gamma is uncharged. Penetration and ionisation comparisons need an energy and absorber context. Dense internal ionisation can be hazardous even for short-range radiation.

Count rate = recorded count / duration
Net source rate = total rate - background rate

Activity in Bq counts decays per second. Detector rate counts recorded events per second. They are related only through the stated emission and detection conditions. For unequal durations in a stable-rate series, pool counts over the total time; do not give every interval equal weight.

Decay is spontaneous and random for an individual nucleus. A large population has a predictable statistical trend, with fluctuations in finite counts. Repeats do not remove an incorrect background or changing geometry.

Half-life and time dependence

After one, two and three half-lives, the expected parent population, activity or proportional corrected rate is 1/2, 1/4 and 1/8 of its initial value. Halve a background-subtracted rate. The raw total tends towards background rather than zero.

A = λN
N = N0e-λt
A = A0e-λt
λt1/2 = ln(2)

For fixed detection conditions, ln(r/r0) versus t has gradient -λ. Preserve zero and negative corrected records but do not logarithmically fit them as zero. Near-background positive points also need an uncertainty judgement. A fitted half-life from constructed values checks a model calculation; it does not establish experimental agreement.

Applications need two kinds of reasoning

Explain the penetration or ionisation that makes the task possible, then relate half-life to its preparation, measurement or operating interval. A thickness gauge needs partial transmission over the useful range. An externally detected internal tracer needs radiation that escapes tissue. Treatment and sterilisation use damage from ionisation, with suitable penetration and controlled exposure.

Longer half-life is not universally preferable. Physical half-life is distinct from biological clearance. Irradiation is exposure to radiation; contamination is the presence of radioactive material.

Conservation and binding

Balance total nucleon number and charge across all particles. Alpha emission changes the daughter by ΔA = -4 and ΔZ = -2. Beta-minus leaves A unchanged and raises daughter Z by one. Gamma leaves A and Z unchanged while reducing nuclear energy.

For a fixed beta-decay branch, a two-product model would fix the electron energy. Its continuous energy spectrum and a missing momentum vector support an additional emitted particle. Energy and momentum conservation apply to the complete account.

Mass defect = Zmp + (A - Z)mn - mnucleus
Binding energy = Δmc2
Binding energy per nucleon = binding energy / A
Released energy Q = (minitial - mfinal)c2

Keep atomic and nuclear mass conventions consistent and retain digits until after subtraction. Binding energy is the positive energy required for complete separation. A fusion or fission energy account must include every reactant and product, including free neutrons.

The binding-energy-per-nucleon curve rises steeply across light nuclei, with helium-4 (about 7.1 MeV) above its neighbours. It peaks at about 8.8 MeV near A = 56 (iron and nickel) and falls slowly to about 7.6 MeV for uranium. Fusion of light nuclei and fission of heavy nuclei both move towards the peak. The products then have greater total binding energy and less rest mass, and the mass difference is released as energy. Compare total binding energies for a reaction by multiplying each per-nucleon value by its own nucleon count.

Nuclear quantities, symbols and units
QuantitySymbolUnit or meaning
Nucleon, proton and neutron numbersA, Z, NDimensionless counts; neutron N = A - Z
Number of specified particles or parent nucleiNDimensionless count
Amount of substancenmol
Avogadro constantNAmol-1
Molar massMkg/mol; g/mol when paired with g
Sample or particle massmkg; u for a specified particle
Atomic, electron, proton and neutron massesma, me, mp, mnkg or u; state which entity
ActivityABq = decays per second
Detected count ratercounts/s or counts/min
Time and half-lifet, t1/2s; convert min consistently
Decay constantλs-1 for t in s
Energy, including binding energyEJ, eV or MeV
Energy released per reactionQJ or MeV
Vacuum light speedcm/s

A denotes a nucleon count in nuclide notation and activity in a decay-rate equation; identify the context and unit. N can denote neutron number A - Z or the remaining parent population. Dimensionless counts can also be labelled n or m under a stated convention; in this chapter n denotes amount in mol and m denotes mass. Read the definition and unit before substituting.

Supplied rounded conversions:
1 u = 1.66 × 10-27 kg
1 u c2 = 931.5 MeV
1 eV = 1.60 × 10-19 J
1 MeV = 1.60 × 10-13 J

Before reporting an answer, check the named entity, time unit, background correction, mass convention and whether the requested energy is total or per nucleon.

Practise exam questions

Write your answer first, then tick the mark points it makes.

Exam-style question

Define the binding energy of a nucleus. [2]

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Exam-style question

A helium-4 nucleus has a mass of 4.00151 u. A proton has a mass of 1.00728 u and a neutron 1.00867 u. Taking 1 u as equivalent to 931.5 MeV, calculate the binding energy per nucleon of helium-4. [4]

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Exam-style question

Use the variation of binding energy per nucleon with nucleon number to explain why energy is released both when light nuclei fuse and when a heavy nucleus splits. [3]

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Exam-style question

Sketch a graph of binding energy per nucleon against nucleon number A for A from 1 to 240. Label the values and features an examiner would look for. [4]

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Exam-style question

Data-based question: A radioisotope generator on a space probe [20]

Space probes sent far from the Sun cannot rely on solar panels. Instead they carry a radioisotope generator. It contains plutonium-238 (proton number 94), which decays by alpha emission to uranium-234 with a half-life of 87.7 years. The alpha particles are absorbed inside the fuel and its casing, which become hot. Thermocouples convert part of this heat into electrical energy; the rest is radiated away by cooling fins.

Table 1. Generator data
mass of plutonium-238 at launch4.0 kg
molar mass of plutonium-2380.238 kg mol-1
kinetic energy of each alpha particle5.59 MeV
efficiency of conversion from heat to electrical energy6.0%
output voltage28 V
1 year3.16 x 107 s
Table 2. Measured electrical power output during the mission
time after launch / years05101520
power / W1361221109989
  1. (a) Write the nuclear equation for the decay of plutonium-238. [2]
  2. (b) Explain why an alpha emitter with a half-life of several decades is chosen for this use. [3]
  3. (c) Show that the decay constant of plutonium-238 is about 2.5 x 10-10 s-1. [1]
  4. (d) Calculate the number of plutonium-238 nuclei at launch. [1]
  5. (e) Calculate the activity at launch and the rate at which heat is produced. [3]
  6. (f) State one assumption you made in (e). [1]
  7. (g) Calculate the electrical power at launch and the current supplied at 28 V. [2]
  8. (h) Calculate the electrical power expected after 20 years if only radioactive decay reduced it. [2]
  9. (i) Use Table 2 to evaluate whether radioactive decay alone explains the fall in output. [3]
  10. (j) If the cooling fins failed, all the heat would go into the 10 kg fuel capsule, of average specific heat capacity 500 J kg-1 K-1. Calculate the initial rate of rise of its temperature. [2]

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Quick recall

Card 1 of 10. Answer in your head, then check.

Most alpha particles pass through a thin foil with little deflection, while very few are scattered through large angles or backwards. Which inference is supported?