Chapter revision
Revision summary
Key ideas, equations and common mistakes. Open any topic below for the full explanation.
Identify what is being counted, what is actually detected and which energy account is complete. Those decisions come before substituting numbers.
Structure and evidence
Most alpha particles passing a thin foil are little deflected; rare large deflections support a small concentration of positive charge and mass. A nucleus has Z protons and A - Z neutrons. A neutral atom has Z electrons. Isotopes have the same Z and different neutron counts; ionisation changes electrons without changing the nucleus.
Count the named entity
N = nNA
NA = 6.02 × 1023 mol-1
Match the mass and molar-mass units. An atom has one nucleus; a molecule can have several. Relative atomic mass Ar and relative molecular mass Mr are dimensionless, while individual mass and molar mass have units.
Radiation and detection
Alpha is a helium-4 nucleus, beta-minus an electron from a nuclear process, and gamma an electromagnetic photon. Alpha and beta have opposite electric-force directions; gamma is uncharged. Penetration and ionisation comparisons need an energy and absorber context. Dense internal ionisation can be hazardous even for short-range radiation.
Net source rate = total rate - background rate
Activity in Bq counts decays per second. Detector rate counts recorded events per second. They are related only through the stated emission and detection conditions. For unequal durations in a stable-rate series, pool counts over the total time; do not give every interval equal weight.
Decay is spontaneous and random for an individual nucleus. A large population has a predictable statistical trend, with fluctuations in finite counts. Repeats do not remove an incorrect background or changing geometry.
Half-life and time dependence
After one, two and three half-lives, the expected parent population, activity or proportional corrected rate is 1/2, 1/4 and 1/8 of its initial value. Halve a background-subtracted rate. The raw total tends towards background rather than zero.
For a supplied fractional-decay model with half-life t1/2:
= exp[-ln(2)t/t1/2]
t = -t1/2ln(r/r0)/ln(2)
The ratio and exponent are dimensionless. Use matching time units; a positive corrected ratio is required before taking its logarithm.
Applications need two kinds of reasoning
Explain the penetration or ionisation that makes the task possible, then relate half-life to its preparation, measurement or operating interval. A thickness gauge needs partial transmission over the useful range. An externally detected internal tracer needs radiation that escapes tissue. Treatment and sterilisation use damage from ionisation, with suitable penetration and controlled exposure.
Longer half-life is not universally preferable. Physical half-life is distinct from biological clearance. Irradiation is exposure to radiation; contamination is the presence of radioactive material.
Conservation and binding
Balance total nucleon number and charge across all particles. Alpha emission changes the daughter by ΔA = -4 and ΔZ = -2. Beta-minus leaves A unchanged and raises daughter Z by one. Gamma leaves A and Z unchanged while reducing nuclear energy.
Binding energy = Δmc2
Binding energy per nucleon = binding energy / A
Released energy Q = (minitial - mfinal)c2
Keep atomic and nuclear mass conventions consistent and retain digits until after subtraction. Binding energy is the positive energy required for complete separation. A fusion or fission energy account must include every reactant and product, including free neutrons.
The binding-energy-per-nucleon curve rises steeply across light nuclei, with helium-4 (about 7.1 MeV) above its neighbours. It peaks at about 8.8 MeV near A = 56 (iron and nickel) and falls slowly to about 7.6 MeV for uranium. Fusion of light nuclei and fission of heavy nuclei both move towards the peak. The products then have greater total binding energy and less rest mass, and the mass difference is released as energy. Compare total binding energies for a reaction by multiplying each per-nucleon value by its own nucleon count.
| Quantity | Symbol | Unit or meaning |
|---|---|---|
| Nucleon, proton and neutron numbers | A, Z, N | Dimensionless counts; neutron N = A - Z |
| Number of specified particles or parent nuclei | N | Dimensionless count |
| Amount of substance | n | mol |
| Avogadro constant | NA | mol-1 |
| Molar mass | M | kg/mol; g/mol when paired with g |
| Relative atomic and molecular masses | Ar, Mr | Dimensionless ratios |
| Sample or particle mass | m | kg; u for a specified particle |
| Atomic, electron, proton and neutron masses | ma, me, mp, mn | kg or u; state which entity |
| Activity | A | Bq = decays per second |
| Detected count rate | r | counts/s or counts/min |
| Time and half-life | t, t1/2 | s; convert min consistently |
| Energy, including binding energy | E | J, eV or MeV |
| Energy released per reaction | Q | J or MeV |
| Vacuum light speed | c | m/s |
A denotes a nucleon count in nuclide notation and activity in a decay-rate equation; identify the context and unit. N can denote neutron number A - Z or the remaining parent population. Dimensionless counts can also be labelled n or m under a stated convention; in this chapter n denotes amount in mol and m denotes mass. Read the definition and unit before substituting.
1 u = 1.66 × 10-27 kg
1 u c2 = 931.5 MeV
1 eV = 1.60 × 10-19 J
1 MeV = 1.60 × 10-13 J
Before reporting an answer, check the named entity, time unit, background correction, mass convention and whether the requested energy is total or per nucleon.
Practise exam questions
Write your answer first, then tick the mark points it makes.
Exam-style question
Define the binding energy of a nucleus. [2]
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Exam-style question
A helium-4 nucleus has a mass of 4.00151 u. A proton has a mass of 1.00728 u and a neutron 1.00867 u. Taking 1 u as equivalent to 931.5 MeV, calculate the binding energy per nucleon of helium-4. [4]
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Exam-style question
Use the variation of binding energy per nucleon with nucleon number to explain why energy is released both when light nuclei fuse and when a heavy nucleus splits. [3]
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Exam-style question
Sketch a graph of binding energy per nucleon against nucleon number A for A from 1 to 240. Label the values and features an examiner would look for. [4]
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Exam-style question
Data-based question: The americium-241 smoke detector [15]
Many smoke detectors contain a tiny sample of americium-241 (proton number 95), which decays by alpha emission to neptunium-237 with a half-life of 432 years. The alpha particles ionise the air between two metal plates connected to a battery. The ions move to the plates, so a small current flows. When smoke enters, ions attach to the smoke particles and move much more slowly, the current falls, and the alarm sounds.
| mass of americium-241 | 0.30 µg |
| molar mass of americium-241 | 0.241 kg mol-1 |
| activity of source | 3.7 x 104 Bq |
| fraction of alpha particles that enter the air gap | 0.50 |
| kinetic energy of each alpha particle | 5.5 MeV |
| average energy needed to make one ion pair in air | 35 eV |
- (a) Write the nuclear equation for the decay of americium-241. [2]
- (b) Explain why an alpha emitter is used rather than a beta or gamma emitter. [2]
- (c) Calculate the number of americium-241 nuclei in the source. [2]
- (d) Calculate the number of ion pairs produced by one alpha particle that stops in the air gap. [1]
- (e) Calculate the maximum current in the air gap. [3]
- (f) State one assumption you made in (e). [1]
- (g) The maker says the source will not need replacing during the detector's 10-year life. Use the data to evaluate this claim. [3]
- (h) Even in clean air, the current fluctuates slightly about its mean value. Suggest why. [1]
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Quick recall
Most alpha particles pass through a thin foil with little deflection, while very few are scattered through large angles or backwards. Which inference is supported?
Review a topic
- Evidence for the nucleus
- Count atoms, nuclei and nucleons
- Alpha, beta and gamma
- Random decay and measured counts
- Half-life and corrected curves
- Choose radiation for a task
- Balance nuclear processes
- Mass defect and binding energy
- Energy from fission and fusion